Preparation of heavily dopedn-type Ge-Si thermoelectric alloys

Germanium-silicon alloys doped with phosphorus were prepared in vacuum by rapidly pouring the molten alloy into cooled copper moulds containing the phosphorus dopant. Without any further treatment, the ingots are milled into powder of grain size (L 5 µm) and hot pressed. It is shown that a high degree of homogenization of the alloy constituents can be obtained in the final compacts, thus eliminating the need for zone-levelled starting material. It is also shown that this work is in agreement with the plastic flow model of sintering known as the Mackenzie-Shuttleworth-McClelland model. Electrical measurements indicate that the dopant is effectively and uniformly incorporated into the alloy.     

Thermoelectric properties of fine grained (75% Sb2Te3-25% Bi2Te3)p-type and (90% Bi2Te3-5% Sb2Te3-5% Sb2Se3)n-type alloys

The thermoelectric properties of fine-grained alloys prepared by either cold pressing and sintering or hot pressing in the range 5–50 m are compared with single-crystal best-direction values. It is shown that for thep-type alloy, almost the entire thermoelectric properties are recovered, i.e. the figure of merit for the finest grain size is almost the same as the best single-crystal value. The same trend is observed in then-type alloy except that 90% of the single-crystal figure of merit is recovered. These results are discussed in terms of a model which suggests that degradation of favourable thermoelectric properties by powdering the alloys is compensated by (1) decrease of thermal conductivity due to scattering of phonons at grain boundaries for grain sizes that are comparable to the mean free path of phonons; and (2) retention of some of the anisotropic properties of the single crystal in the fine-grained compacts.     

Energy Metabolites as Biomarkers in Ischemic and Dilated Cardiomyopathy

With more than 25 million people affected, heart failure (HF) is a global threat. As energy production pathways are known to play a pivotal role in HF, we sought here to identify key metabolic changes in ischemic- and non-ischemic HF by using a multi-OMICS approach. Serum metabolites and mRNAseq and epigenetic DNA methylation profiles were analyzed from blood and left ventricular heart biopsy specimens of the same individuals. In total we collected serum from n = 82 patients with Dilated Cardiomyopathy (DCM) and n = 51 controls in the screening stage. We identified several metabolites involved in glycolysis and citric acid cycle to be elevated up to 5.7-fold in DCM (p = 1.7 × 10⁻⁶). Interestingly, cardiac mRNA and epigenetic changes of genes encoding rate-limiting enzymes of these pathways could also be found and validated in our second stage of metabolite assessment in n = 52 DCM, n = 39 ischemic HF and n = 57 controls. In conclusion, we identified a new set of metabolomic biomarkers for HF. We were able to identify underlying biological cascades that potentially represent suitable intervention targets.     

Design of Dual-Gate P-type IMOS Based Industrial Purpose Pressure Sensor

Silicon - In this treatise, we have proposed a Single Material Gate–Dual Gate Impact Ionization Metal Oxide Semiconductor (SMG DG-IMOS) based Pressure Sensor. The pressure sensor has the most...     

Enhancing the design and performance of a gate-all-around (GAA) charge plasma nanowire field-effect transistor with the help of the negative-capacitance technique

A gate-all-around charge plasma nanowire field-effect transistor (GAA CP NW FET) device using the negative-capacitance technique is introduced, termed the GAA CP NW negative-capacitance (NC) FET. In the face of bottleneck issues in nanoscale devices such as rising power dissipation, new techniques must be introduced into FET structures to overcome their major limitations. Negative capacitance is an efficient effect that can be incorporated into a device to enhance its performance for low-power applications and help to reduce the operating voltage. The Landau–Khalatnikov equation can be applied in such cases to obtain the effective bias. To determine the effects of negative capacitance, lead zirconate titanate (PZT) ferroelectric material, a ceramic material with perovskite properties, is adopted as a gate insulator. This approach diminishes the supply voltage and reduces the power dissipation in the device. Excluding their polarization properties, ferroelectric materials are similar to dielectric materials, and PZT offers abundant polarization with improved reliability and a higher dielectric capacitance. Without proper tuning of the thickness of the PZT material, hysteresis behavior mat occur. Hence, the thickness of the PZT material (t_FE) is an essential parameter to optimize the device performance and achieve a reduced threshold voltage for the GAA CP NW NC-FET device proposed herein. Furthermore, varying the thickness of the PZT ferroelectric material can also enhance the performance. When using the highest values of t_FE, improved outcomes with an analogously lower operating voltage are observed. The effects of varying t_FE on the performance characteristics of the device including the drain current, transconductance, polarized charge, etc. are also interpreted herein.

     

An Eco-Friendly Approach to the Control of Pathogenic Microbes and Anopheles stephensi Malarial Vector Using Magnesium Oxide Nanoparticles (Mg-NPs) Fabricated by Penicillium chrysogenum

The discovery of eco-friendly, rapid, and cost-effective compounds to control diseases caused by microbes and insects are the main challenges. Herein, the magnesium oxide nanoparticles (MgO-NPs) are successfully fabricated by harnessing the metabolites secreted by Penicillium chrysogenum. The fabricated MgO-NPs were characterized using UV-Vis, XRD, TEM, DLS, EDX, FT-IR, and XPS analyses. Data showed the successful formation of crystallographic, spherical, well-dispersed MgO-NPs with sizes of 7–40 nm at a maximum wavelength of 250 nm. The EDX analysis confirms the presence of Mg and O ions as the main components with weight percentages of 13.62% and 7.76%, respectively. The activity of MgO-NPs as an antimicrobial agent was investigated against pathogens Staphylococcus aureus, Bacillus subtilis, Pseudomonas aeruginosa, Escherichia coli, and Candida albicans, and exhibited zone of inhibitions of 12.0 ± 0.0, 12.7 ± 0.9, 23.3 ± 0.8, 17.7 ± 1.6, and 14.7 ± 0.6 mm respectively, at 200 µg mL⁻¹. The activity is decreased by decreasing the MgO-NPs concentration. The biogenic MgO-NPs exhibit high efficacy against different larvae instar and pupa of Anopheles stephensi, with LC50 values of 12.5–15.5 ppm for I–IV larvae instar and 16.5 ppm for the pupa. Additionally, 5 mg/cm² of MgO-NPs showed the highest protection percentages against adults of Anopheles stephensi, with values of 100% for 150 min and 67.6% ± 1.4% for 210 min.     

Face relighting using discriminative 2D spherical spaces for face recognition

As part of the face recognition task in a robust security system, we propose a novel approach for the illumination recovery of faces with cast shadows and specularities. Given a single 2D face image, we relight the face object by extracting the nine spherical harmonic bases and the face spherical illumination coefficients by using the face spherical spaces properties. First, an illumination training database is generated by computing the properties of the spherical spaces out of face albedo and normal values estimated from 2D training images. The training database is then discriminately divided into two directions in terms of the illumination quality and light direction of each image. Based on the generated multi-level illumination discriminative training space, we analyze the target face pixels and compare them with the appropriate training subspace using pre-generated tiles. When designing the framework, practical real-time processing speed and small image size were considered. In contrast to other approaches, our technique requires neither 3D face models nor restricted illumination conditions for the training process. Furthermore, the proposed approach uses one single face image to estimate the face albedo and face spherical spaces. In this work, we also provide the results of a series of experiments performed on publicly available databases to show the significant improvements in the face recognition rates.     

Piezoresistivity in Polymer-Ceramic Composites

Composite materials composed of randomly dispersed semiconducting ceramic particles in an insulating polymer matrix show a pronounced change in resistivity with pressure. Different amounts of iron oxide (Fe₃O₄) powder and antimony-doped tin oxide (SnO₂:Sb) powder were dispersed in an epoxy polymer matrix to form pressure-sensitive composites. In each family of materials, an insulator-to-semiconductor transition is observed in agreement with percolation theory. Composites within a certain range of filler content showed substantial piezoresistive effect under both uniaxial and hydrostatic pressure in which sensitivity is controlled by the choice of filler material and the volume fraction. The effect of temperature on the piezoresistance effect was also examined. Piezoresistors made from Fe₃O₄ composites showed larger temperature changes than those filled with Sb-doped SnO₂.     

Weight loss, polarization, electrochemical impedance spectroscopy, SEM and EDX studies of the corrosion inhibition of copper in aerated NaCl solutions

This work reports results of weight loss, potentiodynamic polarization and impedance measurements on the corrosion inhibition of copper in aerated non-stirred 3% NaCl solutions in the temperature range 15–65 °C using sodium oleate (SO) as an anionic surfactant inhibitor. These studies have shown that SO is a very good ”green”, mixed-type inhibitor. The inhibition process was attributed to the formation of an adsorbed film on the metal surface that protects the metal against corrosive agents. Scanning electron microscopy (SEM) and energy dispersion X-ray (EDX) observations of the electrode surface confirmed the existence of such an adsorbed film. The inhibition efficiency increases with increasing surfactant concentration and time of immersion, while it decreases with solution temperature. Maximum inhibition efficiency of the surfactant is observed at concentrations around its critical micellar concentration (CMC). The potential of zero charge (pzc) of copper was studied by ac impedance, and the mechanism of adsorption is discussed. The sigmoidal shape of the adsorption isotherm confirms the applicability of Frumkin’s equation to describe the adsorption process. Thermodynamic functions for the adsorption process were determined.     

A 60‐GHz on‐chip slot‐array antenna in integrated‐passive‐device technology for antenna‐in‐package applications

A new millimeter‐wave antenna structure on a low‐cost, production platform integrated passive device technology is presented. The antenna consists of a 2‐by‐1 array of slot antennas at 60 GHz. An in‐house developed on‐chip antenna measurement setup was used to characterize the fabricated antenna. The measurement results show an antenna gain of more than 5 dBi with a return loss of 18 dB at 60 GHz. The better‐than‐10‐dB impedance bandwidth of the antenna covers the 60‐GHz unlicensed band from 57 to 64 GHz. The 3‐dB beamwidths of the antenna are 105° and 76° at E‐plane and H‐plane at 60 GHz, respectively. The size of the die of the antenna is 2 mm × 4.5 mm. © 2013 Wiley Periodicals, Inc. Int J RF and Microwave CAE 24:155–160, 2014.